论新型城镇化必须重视产城统筹

在我国工业化与城市化的过程中,产业发展与城市建设的脱节现象已经成为一对比较明显的矛盾,这在城市新区建设和工业园区的发展中表现得尤为突出。产城统筹是推进新型工业化与新型城镇化的有效途径。我国工业化尚未完成,城市化发展正处于关键阶段,在新一轮新型工业化和新型城镇化的过程中,应当注重产业发展与城市建设的有机结合,实现“双轮驱动”,良性发展。     

介孔丝光沸石组装钯物种催化有机反应的研究

随着绿色化学的不断发展,绿色有机合成成为现在及以后有机合成发展的重要方向。本文利用丝光沸石负载金属钯这种非均相催化剂替代传统的均相催化剂对Fujiwara-Moritani反应进行了探索并取得了非常好的效果。     

无机化学实验教学绿色化探索与实践

基于绿色化学的理念,就如何实现无机化学实验的绿色化进行了探索和研究。提出了推行微型化学实验、多媒体仿真技术、"三废"处理、串联实验和现代检测技术应用于无机化学实验中。通过以上措施,加强和培养了师生的环境保护意识,树立了绿色化学的理念。同时,无机化学及实验的绿色化节约了化学试剂,减少有毒有害物质的排放,实现了环境友好化过程。     

关于微型化学实验在化学教学中的应用探究

化学微型实验,顾名思义：“实验药品微量化,实验仪器微型化”。根据微型实验的特点和要求,可以将一些普通的化学实验改造为微型实验,运用微型化的仪器进行化学实验。一方面,降低了实验成本,减少了环境的污染,体现了绿色经济的理念。另一方面,提高了学习者学习化学实验的兴趣,促进了新的教学模式的发展,体现了科学创新的理念。     

带有磺酸基团和羰基酸团的新固体酸的合成及其在缩醛化反应中的催化性能简

The novel solid acid with both sulfonic and carbonyl acid groups has been synthesized from 3-（（2-sulfoethoxy） carbonyl）acrylic acid and tetraethyl orthosilicate （TEOS）. The catalytic activities were investigated through the acetalization. The results showed that the novel solid acid was very efficient for the reactions with the high yields. The high acidity, high stability and reusability were the key feature of the novel solid acid. Moreover, the sulfonic and carbonyl acid groups could cooperate during the catalytic process, which improved its catalytic activities. The catalyst shows recyclability, and hold great potential for replacement of homogeneous catalysts.     

中心城区泵站旱天放江特征及削减潜力分析

中心城区泵站旱天放江产生的臭味已成为严重影响河道水质景观、居民环保投诉的主要问题。该文通过对上海市中心城区近五年泵站放江水量和污染物浓度的分析,明确了旱天放江量近年呈显著下降趋势,旱流放江量是旱天放江减排的重点,雨水泵站是下一步旱天放江控制的重点;泵站旱天放江污染物浓度与当地生活污水水质相近。对于旱流放江和试车放江,可采用工程性措施和管理性措施削减其放江量。中心城区旱天放江有削减潜力的泵站82座,其中应用工程性措施和管理性措施分别能削减旱天放江量约867.95万和908.21万m3,预计总削减量约占2012年旱天放江总量的71.55％。     

特种车辆履带连接件微纳米渗锌工艺

将微纳米渗锌工艺应用到特种车辆履带连接件中,可以显著提高履带连接件的耐磨损、耐腐蚀性能和镀层均匀性,避免零部件发生"锈死"的现象,且微纳米渗锌生产过程中没有三废排放,绿色环保。具有很高的工程价值,经济效益、环境效益显著。     

UV光固化墨水技术及其绿色营销

简要介绍了UV光固化墨水的应用分类、市场预期、技术进展等情况。作为绿色印刷的重要产品之一,阐述了UV墨水在研发、生产、销售过程中,如何利用绿色营销的概念及方法,从营销策略、产品定价、推广渠道、充分利用国家政策等几个方面入手,做好UV墨水生产经营工作。     

Efficient Metal‐Free Aerobic Photooxidation of Sulfides to Sulfoxides Mediated by a Vitamin B2 Derivative and Visible Light

We have developed a metal‐free process for the aerobic photooxygenation of sulfides to sulfoxides mediated by riboflavin tetraacetate or riboflavin (vitamin B₂) photocatalysts and visible light (450 nm) in an acetonitrile‐water (85:15 v/v) mixture. The optimised solvent system leads to both singlet‐oxygen and electron‐transfer pathways in photooxygenation, thus allowing oxidation of electron‐poor and electron‐rich thioanisoles, dialkyl sulfides and sterically hindered sulfides. Besides having a broad substrate scope, the method has very short reaction times and requires low catalyst loading (down to 0.1 mol%). These properties are due to the high photocatalyst stability and the extremely high quantum yields (1.3 for thioanisole oxygenation). Moreover, the method is chemoselective, producing only sulfoxides without overoxidation to sulfones. Taking into account the broad substrate scope, high selectivity and high efficiency, this method distinguishes itself from those previously reported. Other advantages include easy work‐up of the reaction mixture, the availability and biodegradability of the photocatalysts and mild reaction conditions. We demonstrated, on a preparative scale, its practical application in the synthesis of the psychostimulant modafinil, in the selective oxidation of methionine derivatives, and in the detoxification of mustard gas.

     

A framework for governance of public green spaces in cities

Public authorities that seek to transfer the cost of managing green spaces to the private sector face apprehension about the extent of community input in managing of public green spaces in cities. In practice, the governance arrangements for managing public green spaces are neither a purely private or public sector responsibility. They are part of complex and contested governance schemas that involve multiple stakeholder groups with varying interests and responsibilities. This paper proposes a simple framework to support different modes of governance appropriate for the management of public green spaces in cities. The framework classifies stakeholders’ desires for engagement based on ecosystem service characteristics defined on a spectrum of excludability and rivalry. The framework is applied to case studies in Australia and Canada. Finally, we discuss the new insights for governance arrangements for public green space management in cities.